Course Profile   Chemistry (SCH4C), College Preparation, Catholic

 

Unit 5:  Chemistry in the Environment

Time:  27 hours

 

Activity 1 | Activity 2 | Activity 3 | Activity 4 | Activity 5

 

Unit Description

In this unit, students study chemistry as it relates to the quality of the environment. Students build on their knowledge of acids and bases from Grade 10 Science and the chemical calculations involving solutions from Unit 2, Chemical Calculations. Students focus on the importance of a healthy environment with clean air and water. Lastly, students assemble the Environmental Educational Kit for the Course Culminating Task using the materials collected in their Portfolio from each unit.

In the first cluster, students identify gases in the atmosphere that affect air quality and the substances in water that must be measured and controlled to ensure that it is safe for human use and consumption. Students recognize the importance of the atmosphere and water in supporting life on earth and reflect on water as a symbol in the sacraments and rituals of the Catholic Faith. Students examine case studies to explain the need for quantitative analysis of substances in air and water samples to maintain healthy ecosystems.

In the second cluster, students define acids and bases according to the Arrhenius theory and explain the differences between strong and weak acids and bases. Students demonstrate an understanding of concentrated and dilute acids and explain the safety procedures followed in diluting concentrated acids. Through experimentation, students demonstrate the acid-base character of solutions of oxides of metals and non-metals and compare these solutions to the substances present in acid rain.

In the third cluster, students explain the effect of temperature and pressure on a fixed volume of gas. Students identify the gases responsible for acid rain, the reactions involved in the formation of acid rain, and the chemical methods used to reverse the process, for example, neutralization. Students write balanced chemical equations to represent neutralization reactions.

In the fourth cluster, students further develop their scientific investigative skills by using techniques involved in the effective and accurate quantitative analyses of solutions effectively and accurately. Through laboratory activities, students perform an acid-base titration to determine the concentration of an acid or base, and determine the concentration of dissolved ions in a water sample by using gravimetric and colorimetric methods.

In the fifth cluster, students research government regulations on air and water quality, and discuss how individuals can contribute to improvements in the environment. Students plan, organize, and participate in a Plan of Action panel discussion. Furthermore, students assess the environmental, economic, and societal implications of methods of use and disposal of common household products. Students demonstrate an awareness of the need for both government and individuals to ensure a healthy environment for the common good of society. As informed citizens, students make decisions based on both scientific information and ethical and Gospel values. In addition, throughout the unit, students recognize their role as stewards of the earth in addressing Canada’s environmental concerns and issues.

Throughout this unit, students research, learn and develop an understanding of the concepts related to chemistry in their environment in order to assess a local issue, and they develop a plan of action to improve the environment in their community by producing a bulletin for the Course Culminating Task.

Note: If an expectation is in parentheses in a cluster, it is being introduced in that cluster, but not assessed. In addition, at the start of this unit, a diagnostic tool should be used to assess students’ knowledge of acids and bases.

Unit Synopsis Chart

Activity

Time

Learning Expectations

Assessment Categories

Tasks

1. Our Environment
1.1 Air and water quality
1.2 Monitoring air and water

2.5 h

CEV.01, .03, CE1.06, 1.07, (2.01), 3.03
SIS.05, .06, .08
CGE, 1d, i, 2e, 3b, 7d, i, j

Knowledge/ Understanding
Inquiry
Communication
Making Connections

·     Diagnostic Assessment

·     Web maps on air and water quality

·     Examining air and water case studies

·     Poster on monitoring substances in ecosystems

2. Acids and Bases
2.1 Acids and bases
2.2 Metal and non-metal oxides

4 h

CEV.01, .02, CE1.02, 1.03, 1.05, (2.01), 2.03
SIS.01, .02, .03, .04, .05, .06
CGE, 1e, 2b, 4f, 7b, d

Knowledge/ Understanding
Inquiry
Communication

·     Guided inquiry on acids and bases

·     Conductivity measurements of acids and bases

·     Demonstrating acid-base characteristics of metal and non-metal oxide solutions

3. Gases and Acid Rain
3.1 Qualitative relationships of gases
3.2 News Report on acid rain
3.3 Balancing neutralization reactions

5 h

CEV.01, .02, CE1.01, 1.04, 2.04, (2.01, 2.03)
SIS.01, 02, 03, 04, 05, .06
CGE, 1d, 2e, 3b, c, 4f, 7i, j

Knowledge/ Understanding
Inquiry
Communication

·     Activities demonstrating the effect of pressure and temperature on a volume of a fixed quantity of a gas

·     News Report on acid rain

·     Balancing neutralization reactions

·     Quiz

4. Measuring Pollutants
4.1 Quantitative analysis of dissolved ions in water samples
4.2 Titration

4.5 h

CEV.01, .02, CE1.06, 2.01, 2.02, 2.05, 2.06
SIS.01, .02, .03, .04, .05, .06
CGE, 1d, 2e, 4f, 5a, e

Knowledge/ Understanding
Inquiry
Communication

·     Water analysis report

·     Colorimetric and gravimetric analyses

·     Titration of acetic acid in vinegar

5. An Opportunity for Change
5.1 Plan of Action panel discussion
5.2 Household products
5.3 Course Culminating Task

11 h

CEV.01, .02, .03, CE (1.06, 1.07, 2.01), 3.01, 3.02
SIS.01, .02, .03, .04, .05, .06
CGE, 1d, e, 2e, 3b, c, d, 4f, 5a, 7b, d, i, j

Knowledge/ Understanding
Inquiry
Communication
Making Connections

·     Panel presentations on improving air and water quality

·     Flyer on the use and disposal of household products

·     Unit Test

·     Educational Kit and Final Water/Soil Analysis

 

Activity 1:  Our Environment

Time:  2.5 hours

Description

In this activity, students examine the environment by identifying the gases in the atmosphere which affect air quality, and identifying substances in environmental water which affect water quality. Students recognize the importance of the atmosphere and water in supporting life on Earth. Furthermore, students examine case studies concerning the effects of pollutants on air and water quality and design a poster explaining the need for the quantitative analysis of substances in air and water samples in maintaining healthy ecosystems.

Strand(s) & Learning Expectations

Ontario Catholic School Graduate Expectations

CGE1d - develops attitudes and values founded on Catholic social teaching, and acts to promote social responsibility, human solidarity, and the common good;

CGE1i - integrates faith with life;

CGE2e - uses and integrates the Catholic faith tradition in the critical analysis of the arts, media, technology, and information systems to enhance the quality of life;

CGE3b - creates, adapts, and evaluates new ideas in light of the common good;

CGE7d - promotes the sacredness of life;

CGE7i - respects the environment and uses resources wisely;

CGE7j - contributes to the common good.

Strand(s):  Chemistry in the Environmental

Overall Expectations

CEV.01 - demonstrate an understanding of the nature and role of elements and compounds in the environment, including acids and bases, and gases in the atmosphere;

CEV.03 - assess the effects and the implications for society of the levels of various substances in the environment, and demonstrate an awareness of the need for both government and individual citizens to take measures that will ensure a healthy environment.

Specific Expectations

CE1.06 - identify substances in environmental water (including ions that contribute to hardness) whose concentration must be measured and controlled to ensure that the water is fit for human use;

CE1.07 - identify gases in the atmosphere that affect air quality;

CE3.03 - explain the importance of quantitative analysis of substances in air and water samples.

Scientific Investigation Skills

SIS.05 - select and use appropriate numeric, symbolic, graphical, and linguistic modes of representation to communicate scientific ideas, plans, and experimental results;

SIS.06 - select, integrate, and interpret information derived from experiments and from print and electronic sources, including Internet sites, and, either in writing or using a computer, compile and display the information in various forms, including diagrams, tables, graphs, and laboratory reports;

SIS.08 - select and use appropriate SI units.

Prior Knowledge & Skills

·     Science Investigative Skills (SIS)

·     Grade 10 Science: Chemistry, Biology, and Earth and Space Science

·     Grade 9 Science: Chemistry

Planning Notes

·     Air and water quality affecting our environment are introduced in Activity 1 to stress their significance and to provide a focus for the entire unit. Acid rain is addressed in more detail in Activities 2 and 3.

·     Gather the resources, e.g., print, video clips, photos, for Activity 1.1 on the problems or issues arising from pollutants, e.g., global warming, acid rain, toxic substances in water, excess nutrients in water, sedimentation, ozone depletion, smog, etc., and prepare all materials required, e.g., chart paper, markers, posters, etc. These topics are revisited in Activity 5 of this unit.

·     For Activity 1.1, provide students with a list of pollutants, e.g., carbon dioxide, methane, carbon monoxide, volatile organic compounds, nitrogen oxides, sulfur oxides, particulate materials, chlorofluorocarbons, stratospheric ozone, heavy metals, inorganic ions, pesticides, petroleum products, detergents, acids, polychlorinated biphenyls, etc., to categorize as affecting air and/or water quality.

·     Make arrangements to have the students visit the school library/resource centre as required. If it is not available, collect resources for classroom use or arrange Internet access for Activity 1.2.

·     Gather case studies on the environment for Activity 1.2. These should reflect Canadian concerns, e.g., use of pesticides in farming, affects of acid rain on trees and buildings, local water problems, polar bear extinction, effects of air pollution on the health of Canadians, effects of water contaminants on fish, etc.

·     In Activity 1.2, each group is assigned an air substance and a water substance that can be monitored, e.g., dissolved oxygen in water, carbon dioxide in air, lead, ozone, nitrates, etc. The students work together to research information on the acceptable concentrations of the substance in Ontario’s drinking water and the current concentration of the gas in the atmosphere. They determine how changing the concentration of the substances researched can affect ecosystems and their surroundings. One member of the group designs an air poster and the other designs a water poster depicting what happens to an ecosystem when it is affected positively and adversely by changing the concentration of the air- or water-related substance. They explain why measuring the levels of the substance assigned is important for monitoring the health of the ecosystem and its surroundings. Students could include on their poster a quotation that reflects an environmental stewardship theme from one of a variety of sources, e.g., Bible, Chief Seattle, David Suzuki, etc.

·     Review the ethical use of the Internet with the students.

·     If possible, invite guest speakers from the community and/or plan a field trip in the community to highlight topics presented throughout the unit.

·     It is recommended that a unit test be given before beginning the Course Culminating Task.

Teaching/Learning Strategies

Activity 1.1: Air and Water Quality

The teacher:

·     defines the environment and instructs students to brainstorm the effects of air and water pollution on their environment;

·     defines the terms air quality and water quality, and leads a class discussion on the importance of clean air and water to ensuring a healthy environment;

·     directs students to read Psalm 14:1-6 on God’s Creation, and reads in unison with the class a prayer of gratitude e.g., “A Sunset Psalm of Turning” from Prayers for a Planetary Pilgrim, by E. Hayes;

·     arranges groups and assigns an issue or problem involving air or water quality;

·     directs each group to write a brief description of their topic, and creates a list of the pollutants on chart paper;

·     conferences with groups to provide feedback on their information;

·     directs groups to present their information to the class, and instructs students to prepare a summary sheet for the information presented on each topic;

·     instructs students to categorize the list of pollutants affecting air or water quality, using their summary sheet;

·     directs students to prepare a web map on air quality and water quality, identifying gases in the air affecting air quality, and substances in water affecting water quality;

·     collects the web maps on air and water quality for assessment;

·     instructs students to read passages from Scripture and write a reflection in their Journal on the importance of atmosphere and water in supporting life on Earth, and on the importance of water as a symbol in Catholic traditions.

Students:

·     brainstorm the effects of air and water pollution on their environment;

·     read the prayer, and reflect and comment on the importance of air and water to life on Earth;

·     work in groups on the assigned topic, record information on chart paper; and report the findings to the class;

·     record the information on each topic to create a summary sheet and categorize the list of pollutants;

·     write and submit the web map on air and water quality for assessment;

·     read the passages from Scripture that make reference to wind and air, and water, e.g., Genesis 8:1; Exodus 10:13; Numbers 11:31; Proverbs 11:29; Ecclesiastes 1:6; John 3:8; Acts 2:2; 1Kings 19:11-13, Genesis 2:6,10; Exodus 7:18-24; Leviticus 22:6, 2Kings 2:19, Psalm 42:1-2, John 4:7-15, Revelations 7:17, etc.

·     write a reflection in their Journal on the importance of the atmosphere and water to life on Earth and on water as a symbol in Catholic tradition.

Activity 1.2: Monitoring Air and Water

The teacher:

·     groups students in pairs and provides each group with two or more case studies concerning the effects of pollutants on air and water quality;

·     introduces the poster assignment involving the importance of the quantitative analysis of substances in air and water samples;

·     assigns each pair the air- and water-related substances to research;

·     conferences with students to monitor progress;

·     designates one member of the group to design the air poster and the other the water poster, and directs each member of the group to peer assess their partner’s poster prior to the completion of the final product;

·     collects and assesses the posters;

·     instructs students to write a Journal reflection on the need for the study of chemistry and the monitoring of the environment.

Students:

·     read the case studies, pair/share, and summarize the effects of pollution on ecosystems;

·     in pairs, research the assigned air and water substances and determine how concentrations of the substances affect ecosystems and their surroundings;

·     individually prepare the air or water poster, peer assess their partner’s poster, and submit their own poster for assessment;

·     write a reflection in their Journal on the importance of monitoring the air and water for the common good.

Assessment & Evaluation of Student Achievement

·     The web maps on air and water quality may be assessed for Knowledge/Understanding and Communication using a rating scale (CE1.06, CE1.07, SIS.05).

·     The poster may be assessed for Knowledge/Understanding, Communication, and Making Connections using a rubric (CE3.03, SIS.06, SIS.08).

Accommodations

See the Course Overview for general accommodations.

Possible enrichment activities:

·     Identify the major air and water pollutants and their sources in your community.

·     Investigate and write a report on the role of the atmosphere in determining the weather.

·     Compare air and water testing results in your local area to provincial and national values and prepare a presentation for the class.

·     Join or start an environmental club at school to raise an awareness of environmental issues in your community.

·     Prepare a fact sheet evaluating the water purification systems available to homeowners.

·     Explore and explain the use and symbolism of air and water in Scripture.

Resources

Hays, E. Prayers for a Planetary Pilgrim. Easton: Forest of Peace Books Inc., 1999.
ISBN 0-9393516-10-1

Jenkins, F., H. vanKessel, L. Davies, O. Lantz, P. Thomas, and D. Tompkins. Chemistry 11. Toronto: Nelson Thomson Learning, 2002. ISBN 0-17-612101-3

Musto, F., M. Jansen, T. Doram, J. Ivanco, C. Clancy, and A. Ghazariansteja. Chemistry 11. Toronto: McGraw-Hill Ryerson, 2001. ISBN 0-07-088681-4

Rayner-Canham, G., S. Damji, and U. Goering-Boone. Addison Wesley Chemistry 11. Toronto: Pearson Educational Canada, 2001. ISBN 0-201-75048-1

Internet Sites

Air Quality Ontario – http://www.airqualityontario.com

Canada Centre for Inland Waters – http://www.cciw.ca

Chief Seattle’s Thoughts – http://www.webcom.com/duane/seattle.html

Church Documents – http://www.vatican.va

David Suzuki Foundation – http://www.davidsuzuki.org

Encyclopedia of the Atmospheric Environment – http://www.doc.mmu.ac.uk/aric/eae/enter.htm

Environment Canada – http://www.ec.gc.ca

Government of Ontario – http://www.ene.gov.on.ca

The National Air Pollution Surveillance Network – http://www.etcentre.org/naps/

The Ontario Clean Air Alliance – http://www.cleanair.web.net

Videotapes

Chemistry of the Environment. British Columbia: Davis Film and Video Productions, 1993. 34 minutes.

 

Activity 2:  Acids and Bases

Time:  4 hours

Description

In this activity, students use the Arrhenius theory to define acids and bases. They measure the conductivity of acidic and basic solutions to explain the difference between strong and weak acids and bases. Students demonstrate an understanding of concentrated and dilute acids, and explain the safety procedures followed in diluting concentrated acids. Lastly, through experimentation, students demonstrate the acid-base character of solutions of oxides of metals and non-metals and compare these solutions to substances found in acid rain.

Strand(s) & Learning Expectations

Ontario Catholic School Graduate Expectations

CGE1e - speaks the language of life… “recognizing that life is an unearned gift and that a person entrusted with life does not own it but that one is called to protect and cherish it.”

CGE2b - reads, understands, and uses written materials effectively;

CGE4f - applies effective communication, decision-making, problem-solving, time and resource management skills;

CGE7b - accepts responsibility for one’s own actions;

CGE7d - promotes the sacredness of life.

Strand(s):  Chemistry in the Environment

Overall Expectations

CEV.01 - demonstrate an understanding of the nature and role of elements and compounds in the environment, including acids and bases, and gases in the atmosphere;

CEV.02 - use the techniques involved in the quantitative analysis of solutions effectively and accurately.

Specific Expectations

CE1.02 - state and explain the Arrhenius definition of acids and bases;

CE1.03 - explain the difference between strong and weak acids and bases in terms of degree of dissociation;

CE1.05 - demonstrate an understanding of the precise meaning of the terms concentrated and dilute when applied to acids (the terms do not indicate the reactivity of the acid), and explain the safety procedures that must be followed when diluting concentrated acids;

CE2.03 - demonstrate through experimentation the acid-base character of solutions of oxides of metals and non-metals, and compare these solutions to the substances present in acid rain.

Scientific Investigation Skills

SIS.01 - demonstrate an understanding of safe laboratory practices by selecting and applying appropriate techniques for handling, storing, and disposing of laboratory, and using appropriate personal protection;

SIS.02 - select appropriate instruments and use them effectively and accurately in collecting observations and data;

SIS.03 - demonstrate the skills required to plan and carry out investigations using laboratory equipment safely, effectively, and accurately;

SIS.04 - demonstrate a knowledge of emergency laboratory procedures;

SIS.05 - select and use appropriate numeric, symbolic, graphical, and linguistic modes of representation to communicate scientific ideas, plans, and experimental results;

SIS.06 - select, integrate, and interpret information derived from experiments and from print and electronic sources, including Internet sites, and, either in writing or using a computer, compile and display the information in various forms, including diagrams, tables, graphs, and laboratory reports.

Prior Knowledge & Skills

·     Grade 10 Science: Chemistry – acids, bases, neutralization, pH scale

·     Grade 9 Science: Chemistry – metal and non-metals location in Periodic Table

Planning Notes

·     Prepare all handouts and materials as required, e.g., diagnostic test, remedial work, guided inquiry, safety posters, laboratory procedures, indicators, etc.

·     Collect a variety of acidic and basic household products to be identified as acidic or basic, e.g., toilet bowl cleaners, window cleaners, shampoos, vinegar, etc.

·     Make sure all equipment is working properly, e.g., pH meters, conductivity apparatus, etc.

·     Make use of technology if available in your school, e.g., computer interface pH probes and conductivity probes.

·     For the guided inquiry assignment (Appendix A), students should be in groups of three, each with a specific role: reader, recorder, and liaison person. The responsibility of the liaison person is to manage the group and act as a liaison between the teacher and group if clarification is required.

·     Dilute solutions, 0.5 mol · L-1, of acids and bases should be used for the conductivity measurements in Activity 2.1.

·     Remind students to refer to the Chemical Calculations unit for terms related to concentration of solutions and concentration calculations required to carry out the guided inquiry.

·     For Activity 2.2, the oxides may have to be prepared in the lab through combustion experiments. Familiarize yourself with all the reactions and safety precautions, especially the combustion of magnesium and sulfur. The combustion experiments should be teacher demonstrations only. Oxygen gas can be collected by the downward displacement of water, leaving approximately 2 cm of water at the bottom of the gas jar and covering the jar with a glass plate. After the completion of the combustion reaction, dissolve the product formed in the water by shaking the covered gas bottle vigorously. Caution students NEVER TO LOOK DIRECTLY AT THE FLAME when magnesium burns. For the combustion of sulfur, use only a pea-sized piece in a deflagrating spoon and do this experiment in the FUME HOOD. The iron oxide formed by the combustion of steel wool is not soluble in water; therefore, the indicators do not indicate the presence of a base. In addition, the combustion of carbon doesn’t produce enough carbon dioxide to detect the acid using the indicators. The reaction of baking soda and vinegar can be used as an alternative for producing carbon dioxide. The gas can be bubbled in a sample of water and the resulting solution tested. Metallic oxides, e.g., sodium oxide, calcium oxide, etc., found in chemical storerooms can be dissolved in water by students and tested.

·     Ensure the proper disposal of any waste following school board policies.

·     Acid rain discussed in Activity 1 is revisited in Activity 2.2.

Teaching/Learning Strategies

Activity 2.1: Acids and Bases

The teacher:

·     administers a diagnostic test, e.g., matching exercise, true/false, multiple choice, etc., to assess students’ prior knowledge of acids and bases, e.g., properties of acids and bases, pH scale, neutralization, etc., and provides remediation as required;

·     reviews safety in the laboratory when working with acids and bases;

·     reviews how pH and indicators can be used to identify acids and bases;

·     directs students to classify a variety of household substances as acidic or basic using pH and indicators, and checks their results;

·     introduces the Guided Inquiry Activity (Appendix A) on acids and bases;

·     explains the proper safe use of the conductivity apparatus, directs students to the location of all necessary resources, and provides students with the handout;

·     organizes groups and directs students to work on the Guided Inquiry Activity;

·     monitors student progress on the Guided Inquiry Activity;

·     collects and assesses the Guided Inquiry Activity;

·     leads a class discussion on the importance of proper use, handling, and disposal of acids and bases in the home.

Students:

·     complete the diagnostic test and classify a number of substances as acidic or basic;

·     decide the role of each member of the group for the Guided Inquiry Activity;

·     work collaboratively in their groups to complete the Guided Inquiry;

·     individually submit their Guided Inquiry Activity;

·     participate in the discussion on the safety issues associated with acids and bases.

Activity 2.2: Metal and Non-Metal Oxides

The teacher:

·     reviews the relative position of metals and non-metals on the periodic table and summarizes their physical and chemical properties;

·     directs students to list the similarities and differences between metals and non-metals;

·     describes how oxides are formed in combustion reactions;

·     explains the experiment on testing the metallic oxides and non-metallic oxides in water to see if they are acidic or basic;

·     directs students to record their observations, e.g., description of oxide, test of oxide in water using various indicators, for the experiment in chart form in Data Books;

·     demonstrates the burning of magnesium, dissolves the product MgO in water, and tests the resulting solution with various indicators;

·     demonstrates in the fume hood the burning of sulfur, dissolves the product SO2 in water, and tests the resulting solution with various indicators;

·     explains how SO2 causes acid rain, and leads a class discussion on the importance of SO2 in the formation of acid rain and its effects on air and water quality;

·     directs students to conduct the experiments on metallic and non-metallic oxides and complete their observation chart;

·     informs students that lab skills are being assessed;

·     conferences with students to ensure they are working safely and following procedures;

·     assigns questions to analyse the results, e.g., What forms when a metallic oxide reacts with water? What forms when a non-metallic oxide reacts with water? How do the solutions formed compare to the substances found in acid rain?;

·     instructs students to submit Data Books to be assessed.

Students:

·     make a list of similarities and differences between metals and non-metals;

·     record observations of the teacher demonstrations in Data Books;

·     in pairs, conduct experiments on the solution of oxides of metals and non-metals to determine if the solutions are acidic or basic;

·     participate in the discussion on SO2;

·     record all observations and analyse the results;

·     submit Data Books for assessment.

Assessment & Evaluation of Student Achievement

·     The Guided Inquiry Activity may be assessed for Knowledge/Understanding and Communication using a marking scheme (CE1.02, CE1.03, CE1.05).

·     The data analysis for Activity 2.2 may be assessed for Inquiry and Communication using a lab rubric. (CE2.03, SIS.05, SIS.06).

·     Lab skills for Activity 2.2 may be assessed using a lab skills checklist (SIS.01, SIS.02, SIS.03, SIS.04).

Accommodations

See the Course Overview for general accommodations.

·     Computer tutorials can be used for clarifying concepts related to acids and bases.

·     A lab station can be set up for wheelchair access.

Possible enrichment activities:

·     Test the acidity of locally collected rainwater for a month and graph the results.

·     Visit a garden centre and find out how to change the acidity of your soil, and make a list of plants that prefer basic soils and plants that thrive in acidic soils.

Resources

Jenkins, F., H. vanKessel, L. Davies, O. Lantz, P. Thomas, and D. Tompkins. Chemistry 11. Toronto: Nelson-Thomson Learning, 2002. ISBN 0-17-612101-3

Heikkinen, H. Chemistry in the Community: Chem Com, 4th ed., American Chemical Society. New York: W. H. Freeman and Company, 2002. ISBN 0-7167-3551-2

Musto, F., M. Jansen, T. Doram, J. Ivanco, C. Clancy, and A. Ghazariansteja. Chemistry 11. Toronto: McGraw-Hill Ryerson, 2001. ISBN 0-07-088681-4

Rayner-Canham, G., S. Damji, and U. Goering-Boone. Addison Wesley Chemistry 11. Toronto: Pearson Educational Canada, 2001. ISBN: 0-201-75048-1

Shapiro, B. and S. Shapiro. Chemistry at Work. Toronto: Copp Clark Pitman Ltd., 1989.
ISBN 0-7730-4730-1

Computer Software

Chemistry with Computers, Using Logger Pro, Dan D. Homquist and Donald L.Volz, Vernier Software.

Interactive General Chemistry. Tangent Scientific Supply, 2001.

 

Activity 3:  Gases and Acid Rain

Time:  5 hours

Description

Through a series of demonstrations, students determine and explain the qualitative effect of temperature and pressure on the volume of a fixed quantity of gas. Using this information and building on the knowledge from the previous activities, students prepare and present a News Report in the format of a skit or video. In the report, students identify the gases responsible for acid rain and their sources, describe the steps involved in the formation of acid rain, and outline the chemical methods used to reverse the process, e.g., neutralization. Finally, students write balanced chemical equations to represent neutralization reactions.

Strand(s) & Learning Expectations

Ontario Catholic Graduate Expectations

CGE1d - develops attitudes and values founded on Catholic social teaching and acts to promote social responsibility, human solidarity, and the common good;

GGE2e - uses and integrates the Catholic faith tradition in the critical analysis of the arts, media, technology, and information systems to enhance the quality of life;

CGE3b - creates, adapts, and evaluates new ideas in light of the common good;

CGE3c - thinks reflectively and creatively to evaluate situations and solve problems;

CGE4f - applies effective communication, decision-making, problem-solving, time and resource management skills;

CGE7i - respects the environment and uses resources wisely;

CGE7j - contributes to the common good.

Strand(s):  Chemistry in the Environment

Overall Expectations

CEV.01 - demonstrate an understanding of the nature and role of elements and compounds in the environment, including acids and bases, and gases in the atmosphere;

CEV.02 - use the techniques involved in the quantitative analysis of solutions effectively and accurately.

Specific Expectations

CE1.01 - explain in qualitative terms the effect of temperature and pressure on the volume of a fixed quantity of gas;

CE1.04 - identify the gases responsible for acid rain, and describe their sources, the steps in acid rain formation, and the chemical methods used to reverse the process;

CE2.04 - write balanced chemical equations to represent neutralization of acids and bases.

Science Investigation Skills

SIS.01 - demonstrate an understanding of safe laboratory practices by selecting and applying appropriate techniques for handling, storing, and disposing of laboratory materials, and using appropriate personal protection;

SIS.02 - select appropriate instruments and use them effectively and accurately in collecting observations and data;

SIS.03 - demonstrate the skills required to plan and carry out investigations, using laboratory equipment safely, effectively, and accurately;

SIS.04 - demonstrate a knowledge of emergency laboratory procedures;

SIS.05 - select and use appropriate numeric, symbolic, graphical, and linguistic modes of representation to communicate scientific ideas, plans, and experimental results;

SIS.06 - select, integrate, and interpret information derived from experiments and from print and electronic sources, including Internet sites, and, either in writing or using a computer, compile and display the information in various forms, including diagrams, tables, graphs, and laboratory reports.

Planning Notes

·     The importance of safety in the laboratory should be reviewed.

·     Prepare the necessary handouts for each activity, e.g., worksheets, instructions, etc.

·     Ensure that all required materials are available and prepared in advance, e.g., film canisters, balloons, pop cans, etc.

·     The effect of pressure and temperature on the volume of a fixed quantity of gas is explained in qualitative terms only in this activity, but an explanation of the behaviour of ideal and real gases may clear up any possible misconceptions.

·     Activities that demonstrate the effect of pressure on the volume of a fixed quantity of gas that can be used are (a) placing a mini marshmallow in a 50 mL syringe, sealing it and pulling the plunger to reduce the pressure. (b) making a Cartesian diver by placing an eyedropper partly filled with water into a small plastic soda bottle filled to the top with water, sealing, and squeezing the sides of the bottle, (c) filling a syringe with air to the 50 mL mark, sealing and placing textbooks on the plunger to increase the pressure.

·     Activities that demonstrate the effect of temperature on the volume of a fixed quantity of a gas that can be used are: (a) inflating two balloons (about the size of a grapefruit), placing one in a cold water bath and the other in a hot water bath, (b) heating a few corn kernels in a test tube, (c) inverting a pop can with about 10 mL of boiling water into a water/ice bath.

·     Computer interface probes or sensors are available and could be set up for each of the gas activities so that students can gain experience using this technology.

·     There are a number of different computer simulations available with activities on the effects of temperature and pressure on the volume of a gas. These programs might be useful if a student is absent, or to reinforce the learning.

·     The term acid rain in this activity should be expanded to include “acid precipitation.”

·     Review the ethical use of the Internet with your students.

·     Make arrangements to have the students visit the library/resource centre as required. If the school library is not available, collect resources for classroom use or arrange Internet access through your computer department.

Prior Knowledge & Skills

·     Grade 10: Earth and Space Science – air pressure and effect of temperature

·     Grade 10: Chemistry – acids and bases, double displacement reactions

Teaching/Learning Strategies

Activity 3.1: Qualitative Relationships of Gases

The teacher:

·     reviews safety in the laboratory;

·     sets up a series of stations with simple apparatus and instructions, e.g., pop cans, balloons, syringes etc. (see Planning Notes) that illustrate the effects of pressure and temperature on the volume of a fixed quantity of gas;

·     instructs students to design and prepare an appropriate observation chart in their Data Books to record the observations, e.g., volume increased or decreased, or stayed constant;

·     organizes students into pairs and instructs them to move through each station and perform the experiments;

·     summarizes the effect of temperature and pressure on the volume of a fixed quantity of gas on an overhead/board or wall chart using students’ observations, and instructs students to record the summary into their Data Books and to briefly explain observations, and finally submit explanations to be assessed;

·     assesses the summary chart and explanations.

Students:

·     design and prepare an appropriate observation chart in their Data Books to record the observations from each station;

·     working in pairs, carry out procedures outlined at each station, and record all observations;

·     participate in the class discussion and summarize the effects of temperature and pressure on a volume of a fixed quantity of gas;

·     record summary and explain the effect of temperature and pressure on the volume of a fixed quantity of gas in their Data Books;

·     individually, submit the summary chart and explanations to be assessed.

Activity 3.2: News Report on Acid Rain

The teacher:

·     leads a class discussion that relates the information from the web map on the environment
(Activity 1.1), the information obtained on acids and bases (Activity 2.2) and the information on gases (Activity 3.1) to the problem of acid rain/acid precipitation;

·     introduces and describes the News Report project as a group presentation, in the form of a video or skit. The presentation identifies one of the gases responsible for acid rain/acid precipitation, its sources, the steps involved in the formation of acid rain/acid precipitation, and an outline of the method(s) used to reverse the process;

·     organizes students into groups of three and assigns the gas to be studied, e.g., CO2, SO2, NOx, etc.;

·     instructs students to prepare and submit a chart that will be displayed during the presentations, which outlines the Sources, Formation of Acid Rain/Acid Precipitation and Reversal of Process for their gas;

·     arranges for students to visit the library/resource centre;

·     dialogues with the groups to provide guidance, feedback, and to monitor their progress;

·     collects and assesses the completed charts for completion and accuracy;

·     returns assessed charts (prior to presentations) with comments for improvement;

·     instructs students to individually prepare a fact sheet (in the same format as the chart) and to summarize the Sources, Formation of Acid Rain/Acid Precipitation, and Reversal of Process for all the other gases contributing to acid rain/acid precipitation being presented;

·     instructs students to submit their completed fact sheet to be assessed;

·     assesses the presentations of the News Report for Communication.

Students:

·     participate in the class discussion on acid rain/acid precipitation;

·     working in groups of three, research and gather information on their assigned gas;

·     prepare and submit a chart outlining the information gathered on their gas, to be assessed;

·     use the feedback from the assessment to improve the accuracy and completion of their charts;

·     use the information from their charts, to prepare and present a video or skit of their News Report on acid rain/precipitation;

·     individually prepare and complete a fact sheet containing the information presented on the other gases contributing to acid rain/acid precipitation;

·     submit the fact sheet to be assessed.

Activity 3.3: Balancing Neutralization Reactions

The teacher:

·     reviews the balancing of double displacement reactions using various examples, including the neutralization reactions presented in the previous activity;

·     assigns various practice equations for the students to complete;

·     prepares, administers, and assesses a paper-and-pencil quiz on balancing chemical equations that represent the neutralization of acids and bases.

Students:

·     practise balancing and completing chemical equations that represent the neutralization of acids and bases;

·     write a paper-and-pencil quiz on balancing neutralization equations.

Assessment & Evaluation of Student Achievement

·     The observation charts and discussion (explaining the effect of pressure and temperature on the volume of a fixed gas) may be assessed for Knowledge/Understanding, and Inquiry using a suitable checklist (CE1.01) (SIS.01) (SIS.02) (SIS.03).

·     The fact sheet on acid rain may be assessed for Knowledge/Understanding using a checklist, and the News Report may be assessed for Communication using a suitable rubric (CE1.04) (SIS.06).

·     The quiz on balancing chemical equations may be assessed for Inquiry using a suitable marking scheme (CE2.04) (SIS.05).

Accommodations

See the Course Overview for general accommodations.

·     Additional practice problems on balancing chemical equations could be assigned to allow students to improve their problem-solving skills. Students can take advantage of the numerous computer tutorials available.

·     A lab station can be set up for wheelchair access.

Possible enrichment activities:

·     Design and create an computer generated presentation for the News Report;

·     Investigate and job shadow a related career;

·     Research everyday situations that illustrate the effect of pressure and temperature on the volume of a fixed quantity of a gas;

·     Examine the quantitative effect of pressure and temperature on the volume of a fixed quantity of gas, e.g., Boyle’s Law, Charles’ Law.

Resources

Aristov, Natasha and C. Carfille. Acid Rain. The Chemistry of Acid Deposition from the Atmosphere. Madison: Institute for Chemical Education, 1993. ICE Publication 93-007

Harrison, R., D. Fisher, and G. Rayner-Canham. Laboratory Manual Chemistry: A First Course. Don Mills: Addison-Wesley Publishers, 1988. ISBN 0-201-17881-8

Heikkinen, H. Chemistry in the Community: Chem Com, 4th ed., American Chemical Society. New York: W.H. Freeman and Company, 2002. ISBN 0-7167-3551-2

Lynn, David. Understanding Chemistry Laboratory Manual. Toronto: John Wiley & Sons, 1988.
ISBN 0- 471-79695-6

Jenkins, F., H. vanKessel, L. Davies, O. Lantz, P. Thomas, and D. Tompkins. Chemistry 11. Toronto: Nelson Thomson Learning, 2002. ISBN 0-17-612101-3

Musto, F., M. Jansen, T. Doram, J. Ivanco, C. Clancy, and A. Ghazariansteja. Chemistry 11. Toronto: McGraw-Hill Ryerson, 2001. ISBN 0-07-088681-4

Newton, D. Walch Science – Environmental Chemistry. Maine: J. Weston Walch, 1991.
ISBN 0-8251-1914-6

Newton, D. Walch Science - Literacy Series Chemistry. Maine: J. Weston Walch, 1997.
ISBN 0-8251-3311-4

Rayner-Canham, G., S. Damji, and U. Goering-Boone. Addison Wesley Chemistry 11. Toronto: Pearson Educational Canada, 2001. ISBN: 0-201-75048-1

Tocci, Salvatore and C. Viehland. Holt Chemistry Visualizing Matter. Austin: Holt, Rinehart and Winston, 1989. ISBN 0-03-000193-5

Internet Sites

David Suzuki Foundation – http://www.davidsuzuki.org

Encyclopedia of the Atmospheric Environment – http://www.doc.mmu.ac.uk/aric/eae/enter.htm

Environment Canada – http:// www.ec.gc.ca

Environmental Topics – http://environment.about.com

Government of Ontario – http://www.ene.gov.on.ca

National Oceanic and Atmospheric Administration – http://www.education.noaa.gov

pH of rainfall – www.ncdc.noaa.gov

The National Air Pollution Surveillance Network – http://www.etcentre.org/naps/

 

Activity 4:  Measuring Pollutants

Time:  4.5 hours

Description

In this activity, students further develop their communication skills by using appropriate scientific vocabulary to describe ideas related to chemical analysis, e.g., ozone, pH, titration. Students identify the substances in environmental water, both those that contribute to the hardness of water and those that must be controlled to ensure that the water is suitable for human use. Students practise their Scientific Investigative Skills by using techniques involved in the quantitative analysis of solutions by determining the concentration of dissolved ions, e.g., calcium, in a water sample using both gravimetric and colorimetric analysis, and by conducting an acid base titration to determine the concentration of acetic acid in vinegar.

Strand(s) & Learning Expectations

Ontario Catholic School Graduate Expectations

CGE1d - develops attitudes and values founded on Catholic social teaching and acts to promote social responsibility, human solidarity, and the common good;

CGE2e - uses and integrates the Catholic faith tradition in the critical analysis of the arts, media, technology, and information systems to enhance the quality of life;

CGE4f - applies effective communication, decision-making, problem solving, time and resource management skills;

CGE5a - works effectively as an interdependent team member;

CGE5e - respects the rights, responsibilities, and contributions of self and others.

Strand(s):  Chemistry in the Environment

Overall Expectations

CEV.01 - demonstrate an understanding of the nature and role of elements and compounds in the environment, including acids and bases, and gases in the atmosphere;

CEV.02 - use the techniques involved in the quantitative analysis of solutions effectively and accurately.

Specific Expectations

CE1.06 - identify substances in environmental water (including ions that contribute to hardness) whose concentration must be measured and controlled to ensure that the water is fit for human use;

CE2.01 - use appropriate scientific vocabulary to communicate ideas related to chemical analysis;

CE2.02 - use the following instruments correctly and accurately: electronic balance, burette, pH meter;

CE2.05 - conduct an acid-base titration to determine the concentration of an acid or a base;

CE2.06 - determine the concentration of dissolved ions in a water sample, using gravimetric and colorimetric analysis.

Scientific Investigation Skills

SIS.01 - demonstrate an understanding of safe laboratory practices by selecting and applying appropriate techniques for handling, storing, and disposing of laboratory, and using appropriate personal protection;

SIS.02 - select appropriate instruments and use them effectively and accurately in collecting observations and data;

SIS.03 - demonstrate the skills required to plan and carry out investigations using laboratory equipment safely, effectively, and accurately;

SIS.04 - demonstrate a knowledge of emergency laboratory procedures;

SIS.05 - select and use appropriate numeric, symbolic, graphical, and linguistic modes of representation to communicate scientific ideas, plans, and experimental results;

SIS.06 - select, integrate, and interpret information derived from experiments and from print and electronic sources, including Internet sites, and, either in writing or using a computer, compile and display the information in various forms, including diagrams, tables, graphs, and laboratory reports.

Planning Notes

·     Prepare the necessary handouts for each activity, e.g., worksheets, instructions, etc.

·     Ensure that all required materials are available and prepared in advance, e.g., solutions to be tested, burettes, pH meters, colorimeter, MSDS sheets, chemical dictionary, etc.

·     The chemical method, colorimetry, is based on the fact that the intensity of colour in a solution is directly related to the concentration of that coloured substance. Therefore, standard solutions of known concentrations of a coloured ion must be prepared in advance. The students must then compare their coloured solution (of equal volume) to the known standards to determine the concentration of the dissolved ion (see Resources for sample experiment).

·     A spectrophotometer or a colorimeter may be used, if they are available, for the colorimetric analysis, providing a technology link for students.

·     Gravimetric analysis is used to find a relationship between reactants and products by measuring the masses of the products formed in a reaction; therefore an accurate analytical balance should be available for this experiment (see Resources for sample experiments).

·     Describing other methods of analysis, e.g., spectrophotometry, will prevent the misconception that gravimetric and colorimetric analyses are the only accurate quantitative methods of analysis.

·     Computer interfaces, probes, or simulations are also available and could be used for the gravimetric and colorimetric analyses.

·     Test kits for colorimetric analysis are available from most scientific companies.

·     The vinegar used for the titration with 0.1 mol·L-1 sodium hydroxide should be colourless household vinegar, and should be diluted by a factor of 10.

·     Ensure the proper disposal of any waste following school board policies.

·     Review the ethical use of the Internet with your students.

·     Make arrangements to have the students visit the library/resource centre as required. If the school library is not available, collect resources for classroom use, or arrange Internet access through your computer department.

Prior Knowledge & Skills

·     Grade 10: Chemistry – ions

·     Grade 9: Chemistry – lab skills

Teaching/Learning Strategies

Activity 4.1: Quantitative Analysis of Dissolved Ions in Water Samples

The teacher:

·     through a class-directed discussion, uses the information from Activity 1.1 to develop a list identifying the various substances in environmental waters;

·     directs students to use a chemical dictionary and MSDS sheets to identify the potential hazards of the substances on the list;

·     instructs students to categorize the substances, based on their potential hazards, into substances that contribute to the hardness of water and those that make water unfit for human use;

·     directs students to prepare a report that a technician working for a water testing company would submit based on an analysis of a water sample from a homeowner’s new well. The report explains the technician’s results to the clients by identifying and classifying any possible contaminants in the water and describes any risks or hazards associated with the use of the water;

·     collects and assesses the water analysis report;

·     reflects with students on the importance of ensuring that all water is safe for human use;

·     describes the lab report format for the colorimetric analysis experiment;

·     selects an ion to be measured, e.g., calcium or phosphorus, and describes the procedure for the colorimetric analysis;

·     directs students to perform the colorimetric analysis on a given water sample and to determine the concentration of the dissolved ion in the water sample;

·     conferences with students as they perform the analysis to ensure proper lab technique;

·     collects and assesses lab reports;

·     describes the gravimetric method of analysis, and instructs students that Scientific Investigative Skills will be assessed during the experiment;

·     directs students to perform the gravimetric analysis (using the same water sample used in the colorimetric analysis) and to determine the concentration of the dissolved ion in the water sample;

·     conferences with students as they perform the analysis, and assesses their Scientific Investigative Skills;

·     through a class-directed discussion, compares the benefits of each method of analysis.

Students:

·     participate in preparing the list of substances found in environmental waters;

·     use the MSDS sheets and chemical dictionary to prepare and submit the water analysis report;

·     reflect on the importance of ensuring that all water is safe for human use;

·     perform a colorimetric analysis on a water sample and use the data collected to determine the concentration of the dissolved ion;

·     prepare and submit the colorimetric lab report to be assessed;

·     perform a gravimetric analysis on the same water sample, and determine the concentration of the dissolved ion in the water sample;

·     conference with the teacher during their analysis and demonstrate proper safety procedures and lab skills;

·     participate in the class discussion comparing the two methods of analyses.

Activity 4.2: Titration

The teacher:

·     describes a titration as a common procedure used to determine the concentration of substances in solutions;

·     relates the calculations needed to determine the concentration of the unknown acid (CAVA = CBVB) to those used when diluting solutions in Unit 2 (C1V1 = C2V2);

·     demonstrates the proper technique for performing a titration of an acid with a base, and directs students to illustrate this technique in the Inquiry Skills section of their Data Books;

·     directs students to prepare an observation chart in Data Books, e.g., Volume of acid, Volume of base, Concentration of base, and to complete the titration;

·     conferences with students as they perform the titration, to ensure proper lab technique;

·     directs students to submit observation charts and calculations to be assessed;

·     assesses the observation charts and calculations;

·     instructs students to individually prepare a glossary of all the scientific vocabulary related to chemical analysis used in this unit, and to prepare a crossword puzzle and answer sheet using these terms;

·     instructs students to exchange crosswords with one another, solve the crosswords without the aid of their glossary, and submit the completed crossword to be assessed;

·     assesses all completed crossword puzzles.

Students:

·     illustrate the titration technique in the Inquiry Skills section of their Data Books;

·     prepare an observation chart in Data Books;

·     perform the titration and determine the concentration of acetic acid in vinegar;

·     submit Data Books with the observation charts and titration calculations to be assessed;

·     write a glossary of all the related scientific vocabulary, then prepare a crossword puzzle and answer sheet;

·     complete one another’s crossword puzzles without the aid of a glossary;

·     submit the completed crossword puzzle to be assessed.

Assessment & Evaluation of Student Achievement

·     The water analysis report may be assessed for Knowledge/Understanding using a suitable checklist (CE1.06) (SIS.01),

·     The lab report on the colorimetric analysis of a dissolved ion may be assessed for Inquiry and Communication using a suitable rubric (CE2.06) (CE2.02) (SIS.04) (SIS.05) (SIS.06).

·     Student lab performance skills in the gravimetric analysis may be assessed for Inquiry using a suitable rubric (CE2.06) (SIS.01) (SIS.02) (SIS.03).

·     The observation chart and calculations for the titration may be assessed for Inquiry, Communication, and problem-solving skills using a suitable marking scheme (CE2.05) (SIS.03) (SIS.05) (SIS.06).

·     The crossword puzzle may be assessed for Communication using a suitable checklist (CE2.01).

Accommodations

See the Course Overview for general accommodations.

·     Sample data for the colorimetric analysis can be supplied to any student who is visually challenged in identifying colour;

·     A lab station can be set up for wheelchair access;

·     Large print scales on instruments or burettes can be used for visually challenged students.

Possible enrichment activities:

·     Visit an industry or lab that uses a large-scale version of the analytic techniques used in this activity;

·     Research various pollutants in local waters and explain how they are analysed;

·     Determine the amount of water you would have to drink per day to get your minimum requirement of calcium from water that contains 300 ppm calcium carbonate;

·     Prepare a chart listing concentration levels of pollutants during each of the seasons, and investigate the problems arising because of this, both in terms of health issues, and in terms of cleanup processes and costs to consumers so that humans can safely consume the water.

Resources

Harrison, R., D. Fisher, and G. Rayner-Canham. Laboratory Manual Chemistry A First Course. Don Mills: Addison-Wesley Publishers, 1988. ISBN 0-201-17881-8

Heikkinen, H. Chemistry in the Community: Chem Com, 4th ed., American Chemical Society. New York: W.H. Freeman and Company, 2002. ISBN 0-7167-3551-2

Holmquist, Dan and Donald Volz. Chemistry With Computers Using Logger Pro. Portland: Vernier Software, 1997. ISBN 0-916731-95-X

Jenkins, F., H. vanKessel, L. Davies, O. Lantz, P. Thomas, and D. Tompkins. Chemistry 11. Toronto: Nelson Thomson Learning, 2002. ISBN 0-17-612101-3

Lynn, David. Understanding Chemistry Laboratory Manual. Toronto: John Wiley & Sons, 1988.
ISBN 0- 471-79695-6

Rayner-Canham, G., S. Damji, and U. Goering-Boone. Addison Wesley Chemistry 11. Toronto: Pearson Educational Canada, 2001.

 

Activity 5:  An Opportunity for Change

Time:  11 hours

Description

In this activity, students research issues concerning air and water quality in Canada, government regulations and initiatives, individual actions to improve air and water quality. The students plan, organize, and participate in a Plan of Action panel discussion. In addition, students assess the environmental, economic, and societal implications of methods of use and disposal of common household products. They demonstrate an awareness of the need for both government and individuals to ensure a healthy environment for the common good of humankind. Furthermore, students recognize their role as stewards of the Earth in addressing Canada’s environmental concerns and issues. Lastly, the students assemble the Environmental Educational Kit for the Course Culminating Task.

Strand(s) & Learning Expectations

Ontario Catholic School Graduate Expectations

CGE1d - develops attitudes and values founded on Catholic social teaching and acts to promote social responsibility, human solidarity, and the common good;

CGE1e - speaks the language of life... “recognizing that life is an unearned gift and that a person entrusted with life does not own it but that one is called to protect and cherish it”;

CGE2e - uses and integrates the Catholic faith tradition in the critical analysis of the arts, media, technology, and information systems to enhance the quality of life;

CGE3b - creates, adapts, and evaluates new ideas in light of the common good;

CGE3c - thinks reflectively and creatively to evaluate situations and solve problems;

CGE3d - makes decisions in light of gospel values with an informed moral conscience;

CGE4f - applies effective communication, decision-making, problem-solving, time and resource management skills;

CGE5a - works effectively as an interdependent team member;

CGE7b - accepts accountability for one’s own actions;

CGE7d - promotes the sacredness of life;

CGE7i - respects the environment and uses resources wisely;

CGE7j - contributes to the common good.

Strand(s):  Chemistry in the Environment

Overall Expectations

CEV.01 - demonstrate an understanding of the nature and role of elements and compounds in the environment, including acids and bases, and gases in the atmosphere;

CEV.02 - use the techniques involved in the quantitative analysis of solutions effectively and accurately;

CEV.03 - assess the effects and the implications for society of the levels of various substances in the environment, and demonstrate an awareness of the need for both government and individual citizens to take measures that will ensure a healthy environment.

Specific Expectations

CE3.01 - demonstrate an awareness of how governmental regulations and the actions of individual people can improve air and water quality;

CE3.02 - assess the environmental, economic, and societal implications of methods of use and disposal of common household products.

Scientific Investigation Skills

SIS.05 - select and use appropriate numeric, symbolic, graphical, and linguistic modes of representation to communicate scientific ideas, plans, and experimental results;

SIS.06 - select, integrate, and interpret information derived from experiments and from print and electronic sources, including Internet sites, and, either in writing or using a computer, compile and display the information in various forms, including diagrams, tables, graphs, and laboratory reports.

Prior Knowledge & Skills

·     Science Investigative Skills (SIS)

·     Grade 10 Science: Chemistry, Biology, and Earth and Space Science

·     Grade 9 Science: Chemistry

Planning Notes

·     Students revisit the environmental concerns and issues raised in Activity 1.

·     For Activity 5.1, the teacher acts as a host for the two panel discussions focusing on either Canadian air or water quality. Students are organized in groups of three and are assigned a particular issue, e.g., Great Lakes Action Plan, Canada Water Act, Ontario’s New Drinking Water Protection Regulation, Kyoto Agreement, Clean Air Action Plan, etc. The members of the group represent the government, environment specialist/scientific researcher, or an environmentally conscious citizen. The government representative must provide information on the legislation, What does the legislation say? What regulations are relevant? Who enforces it? Who is affected by the legislation? When was the legislation enacted? The environment specialist/scientific researcher discusses the need for the legislation, e.g., What environmental problem does the regulation address? Who benefits from the legislation? What international agreements pertain here? The environmentally conscious citizen explains how individuals can make a difference, e.g., What lifestyle choices can people make to effect change? How can citizens ensure clean air and water is a priority? For the panel discussion on air quality, all the students assigned to study air quality present their information for their special interest group. The teacher introduces the topic, asks the questions, and directs the discussion. A similar format is followed for the panel discussion on water quality.

·     Encourage students to involve multimedia presentations in their panel discussion.

·     For Activity 5.2, teachers are encouraged to use local resources available from their communities and environmental agencies, and to locate local websites concerning waste disposal of household products. For this activity, students choose a household product to research, e.g., paints, glues, motor oil, batteries, cleaners, expired medicines, etc. They then assess the environmental, economic, and societal implications of methods of use and disposal for their product. Acting as waste management coordinators, students prepare a webpage, newspaper flyer, or letter for the local residents outlining their findings and suggesting ways to produce less waste, e.g., environmentally safe alternatives for cleaners and pesticides.

·     A unit test should be prepared and administered before starting the final assembling of the Educational Kit.

·     The Course Culminating Task is assigned in Unit 1 and students work in groups of four throughout the course researching and compiling information in their portfolios. The last five hours of this unit are allotted for the assembling of the Educational Kit and the completion of the final water analysis.

·     The Educational Kit contains a collection of materials that can be used as a resource in a classroom to supplement a topic on the environment. The Kit should be self-contained in a box or package designed by the students, and should consist of an actual water or soil test kit, including reagents, instructions, and sample data sheets similar to test kits that are purchased from scientific companies. It might be helpful to show students some soil or water (swimming pool) test kits that are available. The Kit should also contain other resources that would be useful in a classroom, including videos, career flyers, puzzles, blackline masters, or sample case studies.

·     The student portfolios maintained throughout the semester contain all of the research and information students need to assemble the final Kit, i.e., In Unit 1, students prepare flow charts and/or experimental procedures (including flame tests), and precipitation reactions to determine the presence of ions in an unknown sample. This information is used to prepare the instruction sheet and data charts required to test for the presence of ions in an unknown sample of water, e.g., calcium ions, iron (II) ions, chloride ions, sulfate ions, or to test for substances or ions in an unknown sample of soil, e.g., nitrogen, phosphorus, pH, etc. In Unit 2, students developed and practised the skills required to accurately prepare solutions of known concentrations. The portfolio should contain the calculations or formulae needed to prepare the reagents for the soil or water test kit. In Unit 3, students researched the impact of industrial electrochemical processes on the environment. Students use this information/research to prepare a collage, diagram, small poster, or thought-provoking comic strip to illustrate the impact of metal refining or other industrial electrochemical processes on the production of acid rain. In Unit 4, students researched the environmental risks and benefits associated with the use of organic compounds. Students use this information/research to assess the impact of using organic compounds on the environment and society, and either produce a video or compile a case study illustrating their assessment for the Kit. In Unit 5, students researched and participated in a panel discussion on a particular pollutant and how governmental regulations and the actions of individuals can improve air and water quality. Students use this information to prepare a bulletin outlining a local issue and their plan for improving their local environment.

·     Ensure that all required materials are available and prepared in advance, e.g., chemicals needed for the preparation of the reagents for the water/soil kits, small dropper bottles, construction paper, scissors, glue, any experimental procedures, etc.

·     Prepare in advance, a checklist that itemizes all the components of the Kit. This list should be distributed to students in Unit 1 when the task is first introduced, to allow them ample opportunity to research, organize and prepare for the final assembling of the Kit.

·     Make arrangements to have the students visit the library/resource centre as required. If the school library/resource centre is not available, collect resources for classroom use, or arrange Internet access through your computer department.

·     After the Kits are completed, students use their water/soil test kits to perform a final analysis of a water/soil sample.

·     Prepare and supply students with an unknown water/soil sample in which they measure the pH, perform a titration to accurately determine the acid or base concentration, and identify and determine the concentration of a dissolved metal ion, e.g., calcium ion.

·     Students identify and determine the concentration of the dissolved ion in the water/soil sample using their test kits and one or more of the following procedures: precipitation reactions, flame tests, displacement reactions between metal elements and metal salts, gravimetric analysis, or colorimetric analysis.

Teaching/Learning Strategies

Activity 5.1: Plan of Action Panel Discussion

The teacher:

·     reviews the environmental issues concerning air and water quality;

·     discusses smoking by-laws in and water treatment facilities in the local community to raise the issue of air and water quality;

·     introduces the Plan of Action panel discussion, organizes groups, and assigns topics;

·     conferences with each group to monitor their progress and to ensure that they work cooperatively;

·     instructs students to prepare a summary of their research;

·     acts as host for each panel discussion;

·     assesses the summary and each student’s contribution in the panel discussion;

·     instructs students to update their portfolio with the summaries from each group;

·     leads a discussion on the need for both government and individuals to work together to ensure a healthy environment;

·     directs students to write a reflection discussing the impact of the panel discussion on their lives.

Students:

·     in groups of three, work collaboratively to brainstorm, research, and conference with each other and the teacher to prepare their portion of the panel discussion;

·     prepare materials, e.g., video clips, photos, statistics, etc., to be used during the panel discussion;

·     participate in the panel discussion on air or water quality;

·     update their portfolio with the summaries from each group;

·     write a Journal reflection commenting on the impact the panel discussions have made on their understanding of issues concerning clean air and water and how they can use this knowledge in making informed choices in the future.

Activity 5.2: Household Products

The teacher:

·     leads a class discussion on the common household products found in the kitchen and bathroom, garage and workshop, garden, and general household;

·     introduces the newspaper flyer, webpage, or letter assignment concerning a chosen household product;

·     instructs students to research the methods of use and the disposal of their product in the local area;

·     directs students to assess the impact the use and disposal of their product has on the local environment, economy, and society;

·     assists students during their research and monitors their progress;

·     collects and assesses the product;

·     leads a class discussion on the importance of individuals in effecting change concerning the use and disposal of household products;

·     instructs students to write a reflection in their Journal on the importance of being an informed consumer and how they can effect positive change.

Students:

·     prepare a list of common household products;

·     choose a household product, research, and analyse issues involved in the methods of use and the disposal of the product in their local area;

·     write a letter, prepare a newspaper flyer, or create a webpage to inform citizens in their local area about the household product;

·     submit their completed product for assessment;

·     write a reflection on how they can contribute to a cleaner environment by being informed.

Activity 5.3: Course Culminating Task

The teacher:

·     using various types of educational kits/soil test kits etc., as examples, outlines the format, packaging and timeline needed for the assembling of the Educational Kit, first introduced in Unit 1, and has various types of educational kits/soil test kits displayed in the classroom;

·     reviews the list of the components of the Educational Kit including:

·     a test kit designed to determine the identity of two ions or substances in an unknown sample of water or soil including: the reagents needed for the tests (in dropper bottles); an unknown sample of water or soil; instructions (procedures) to identify the ions or substances; a data sheet to record observations.

·     a collage, diagram, small poster, or thought-provoking comic strip illustrating the impact of industrial electrochemical processes on the production of acid rain;

·     a video or case study which assesses the benefits and risks to the environment associated with the use of organic compounds;

·     a bulletin describing a local environmental issue and a plan for improving the quality of air or water in their region;

·     a pamphlet describing a career in environmental chemistry;

·     a crossword puzzle or word search of terms related to environmental chemistry;

·     an inventory list of the contents of the Kit;

·     arranges for all necessary equipment or materials (dropper bottles, chemicals, scissors, construction paper) to be available in the classroom;

·     directs students to prepare for the final analysis of an unknown water/soil sample;

·     supplies water/soil samples, instructions and equipment, e.g., pH meters, burettes, etc., for the final water/soil analyses and circulates and assesses each student for Scientific Investigative skills;

·     collects and assesses the completed Kits.

Students:

·     in groups of four, work collaboratively to design and plan the assembling of their Educational Kit;

·     design and prepare a package for their Kit and assemble all the contents of the Kit into the package;

·     prepare and perform the analysis on an unknown water/soil sample using their water/soil test kit and any other materials/equipment, e.g., pH meter, burette, colorimeter, etc.;

·     demonstrate proper safety procedures and lab skills as they perform the analysis on the water/soil sample and determine the pH, the concentration of the acid or base, the identity and accurate concentration of the dissolved metal ion in the water/soil sample;

·     submit the completed Kit for assessment.

Assessment & Evaluation of Student Achievement

·     The summary may be assessed for Communication using a rating scale.

·     The panel discussion may be assessed for Knowledge/Understanding, Communication, and Making Connections using a rubric (CE3.01) (SIS.05) (SIS.06).

·     The webpage, flyer, or letter may be assessed for Knowledge/Understanding, Communication, and Making Connections using a rubric (CE3.02) (SIS.05) (SIS.06).

·     The components of the Educational Kit may be assessed for Knowledge/Understanding and Communication using a suitable checklist. The career pamphlet and collage on the effects of industrial processes in electrochemistry, the bulletin on a local environmental issue, and the video on the use of organic products may be assessed for Communication and Making Connections using a suitable rubric. The soil/water test kit may be assessed for Inquiry using an appropriate checklist. The final water/soil analysis may be assessed for Knowledge/Understanding, Inquiry, and Scientific Investigative Skills using a suitable marking scheme. The Course Culminating Task would be included in the Final Evaluation.

Accommodations

See the Course Overview for general accommodations.

Possible enrichment activities:

·     Research air and water quality in developing countries and write a letter to the editor in a local paper, commenting on the role and responsibility of industrialized nations for improving their environment;

·     Write an article for the next edition of the school paper, describing the highlights of the panel discussions;

·     Contact a local environmental group and volunteer to work on a cleanup project in your area;

·     Investigate international responses to protect air and water, and compare them to Canada’s initiatives.

Resources

Baird, C. Environmental Chemistry. New York: W.H. Freeman and Company, 1999.
ISBN 0-7167-3153-3

Draper, D. Our Environment: A Canadian Perspective. Toronto: International Thomson Publishing Company, 1998. ISBN 0-17-605552-5

Heikkinen, H. Chemistry in the Community: Chem Com, 4th ed., American Chemical Society. New York: W.H. Freeman and Company, 2002. ISBN 0-7167-3551-2

Newton, D. Environmental Chemistry. Portland: J. Weston Walch, 1991. ISBN 0-8251-1914-6

Internet Sites

Canada Centre for Inland Waters – http//www.cciw.ca

Environmental issues – http//:www.americanchemistry.com

Environmental Topics – http//:www.learner.org
– http//environment.about.com

Ground-level Ozone/Greenhouse – http//:www.ucar.edu/learn

Global warming – http//:www.education.noaa.gov

Plastics – http//:www.plastics.org

Ministry of the Environment – http//:www.ene.gov.on.ca

National Climate Center – http//:www.ncdc.noaa.gov

The Green Lane – http//www.ec.gc.ca


Appendix A

Acids and Bases

 

Acids and bases are used in our everyday lives. It is important to understand the terms used to describe acidic and basic solutions. This activity focuses on the following questions: What is the Arrhenius definition for acids and bases? What is meant by strong and weak acids and bases? What is the difference between a concentrated and dilute acid? How should acids be diluted?

 

1.   a)   The following reactions represent what happens when acids are dissolved in water.

HCl (aq) ® H+ (aq) + I- (aq)

HF (aq) ® H+ (aq) + F- (aq)

HNO3 (aq) ® H+ (aq) + NO3- (aq)

What ion is common in all these equations?

b)   The equations in 1(a) involve a process called dissociation. What does this mean?

c)   The Arrhenius theory uses dissociation to define an acid. Using the reactions in 1(a) as a guide complete the following definition for an acid. An acid is a substance that ____________ in water to produce ________________.

 

2.   a)   Using the conductivity apparatus, determine and record the conductivity values or the bulb             brightness in a chart for the acids provided. What species is responsible for current flow?
      Explain how the conductivity is related to the extent or degree of dissociation.

b)   What determines the strength of an acid?

c)   Organize the acids from 2(a) from strongest to weakest.

d)   Write an equation for the ionization of each of the acids used in 2(a).
      Use
® for strong acids and « for the weak acids.

 

3.   a)   Both strong and weak acids can be found in concentrated and dilute forms. It is important to         know the concentration of an acid so that proper safety procedures can be followed.
      What does concentration mean?

b)   How do you dilute a stock solution of copper (II) sulfate? Compare the amounts of substances found in the stock solution and the diluted solution.

c)   The following is a list of concentrations of some common laboratory acids.

Concentrated HCl

12 mol/L

Dilute HCl

3 mol/L

Concentrated H2SO4

18 mol/L

Dilute H2SO4

3 mol/L

What is the difference between a concentrated and dilute acid?

d)   Most laboratory acids are corrosive. Explain why a burn from a concentrated acid is more severe than one from a dilute acid.

e)   Explain why acetic acid found in vinegar is safe to consume, but pure acetic acid (glacial acetic acid) is not, even though they are both weak acids.

 


Appendix A  (Continued)

 

4.   Draw a diagram, using a beaker to illustrate the following conditions for an acid HA:

·     HA is a concentrated strong acid

·     HA is a concentrated weak acid

·     HA is a dilute strong acid

·     HA is a dilute weak acid

(Hint: Use the species HA, H+, and A-. Do not draw water molecules. Draw between 2 and 10 HA formula units, or an appropriate number of H+ and A- ions.)

 

5.   The process of mixing a concentrated acid with water to dilute it generates a great deal of heat. Using the safety technique charts in the room, a video clip, or a photo provided by your teacher, describe the proper procedure to follow when diluting a concentrated acid.

 

6.   a)   The following reactions represent what happens when bases are dissolved in water.

NaOH (s) ® Na+ (aq) + OH- (aq)

KOH (s) ® K+ (aq) + OH- (aq)

What ion is common in the above equations?

b)   The Arrhenius theory can also be used to define a base. Does dissociation occur?

c)   Complete the following statement: A base is a substance that __________________ in water to produce _________________.

d)   Describe the difference between a strong base and a weak one.

 

 

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